Reactions of N-polyfluorophenylcarbonimidoyl dichlorides with primary and secondary amines. Kinetics and mechanism. Synthesis of polyfluorinated carbodiimides, …

IV Kolesnikova, TD Petrova, VE Platonov…

Index: Kolesnikova, I. V.; Petrova, T. D.; Platonov, V.E.; Mikhailov, V. A.; Popov, A. A.; Savelova, V.A. Journal of Fluorine Chemistry, 1988 , vol. 40, p. 217 - 246

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Citation Number: 15

Abstract

Abstract The reaction of N-polyfluorophenylcarbonimidoyl dichlorides with primary and secondary aliphatic and aromatic amines have been studied. With primary aliphatic amines, the reactions led to carbodiimides or guanidines, depending on the amount of amine. The carbodiimides obtained reacted with amines to form guanidines. The reactions with primary aromatic amines produced only triarylguanidines. N-Pentafluorophenyllcarbonimidoyl ...

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