Journal of Organometallic Chemistry

Insertion reactions of dialkylaluminium derivatives: VII. Preparative application of the reactions of (dimethylalumino)(trimethylsilyl) methylamine with carbonyl …

T Sakakibara, T Hirabayashi, Y Ishii

Index: Sakakibara,T. et al. Journal of Organometallic Chemistry, 1972 , vol. 46, p. 231 - 242

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Citation Number: 1

Abstract

Abstract Five types of reactions between (dimethylalumino)(trimethylsilyl) methylamine Me 2 Al NMe SiMe 3 and carbonyl compounds (ketones, esters and amides) were found to occur, depending on the structure of the carbonyl compounds. Among others two new interesting compounds, 4-(dimethylamino)-4-(methylamino)-3-buten-2-one CH 3 CO CH C (NHMe) NMe 2 from acetamide and N, O- ...