Water mediated Heck and Ullmann couplings by supported palladium nanoparticles: importance of surface polarity of the carbon spheres

…, V Srinivasulu, BN Seshadri, N Markandeya…

Index: Kamal, Ahmed; Srinivasulu, Vunnam; Seshadri; Markandeya, Nagula; Alarifi; Shankaraiah, Nagula Green Chemistry, 2012 , vol. 14, # 9 p. 2513 - 2522

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Citation Number: 45

Abstract

Heterogeneous palladium nanoparticle catalysts that are supported on amphiphilic carbon spheres (Pd@ CSP) have been utilized for water-mediated Heck coupling reactions of aryl halides with different alkenes under phosphine free as well as aerobic conditions. Furthermore, a variety of Heck coupling reactions using different bases and solvents, including organic polar and non-polar solvents, have been explored. Aryl bromides are ...