A stereocontrolled total synthesis of C-nucleosides.

T Sato, Y Hayakawa, R Noyori

Index: Sato; Hayakawa; Noyori Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 9 p. 2515 - 2525

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Citation Number: 28

Abstract

A stereocontrolled, general synthesis of chiral C-nucleosides has been achieved through a common lactonic C-β-glycoside intermediate which is readily obtainable from non- carbohydrate materials. Osmium tetraoxide-catalyzed vic-dihydroxylation of 8-oxabicyclo [ ...

~93%

~92%

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