Reactions of Pd2+ and Pt2+ with pyrrolidinedithio carbamate and cystine ligands: synthesis and DFT calculations

E Abd Al-Razaq, N Buttrus, W Al-Kattan…

Index: Abd Al-Razaq, Eid; Buttrus, Nabeel; Al-Kattan, Wedad; Aziz Jbarah, Abdel; Almatarneh, Mansour Journal of Sulfur Chemistry, 2011 , vol. 32, # 2 p. 159 - 169

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Citation Number: 3

Abstract

Mono-and dinuclear complexes of the type M (cys), M (PTD) 2 and M2 (PTD) 4, where M= Pd (II) or Pt (II), cys=(SCH 2CH (NH 2) COOH) 2 and PTD= pyrrolidine thiocarbanoyl disulfide, have been prepared through oxidative addition reaction. They are characterized by microanalyses of metal content, molar conductance, magnetic measurements, infrared and UV–visible spectral studies. The experimental infrared data are supported by density ...