Carbonylation of hydrocarbylpalladium (II) complexes containing substituted pyridinecarboxylate chelating ligands. Steric and electronic manipulation of the CO- …

JL Hoare, KJ Cavell, R Hecker, BW Skelton…

Index: Hoare, Jason L.; Cavell, Kingsley J.; Hecker, Richard; Skelton, Brian W.; White, Allan H. Journal of the Chemical Society - Dalton Transactions, 1996 , # 11 p. 2197 - 2205

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Citation Number: 33

Abstract

Organopalladium (II) complexes of general formula [PdR (N–O) L][R= Ph, N–O= pyridinecarboxylate (pyca), L= P (C6H11) 3; R= Ph, N–O= 6-methylpyridinecarboxylate (mpyca), L= PPh3, PMePh2, P (C6H11) 3 or PEt3; R= Ph, N–O= 4-nitropyridinecarboxylate (npyca), L= P (C6H11) 3; R= Ph, N–O= 6-methyl-4-nitropyridinecarboxylate, L= P (C6H11) 3; R= Me, N–O= mpyca, L= PPh3, P (CH2Ph) 3 or P (C6H11) 3; R= Me, N–O= npyca, L= ...