Reactivity and regiochemical behavior in the solvolysis reactions of (2, 2-difluorocyclopropyl) methyl tosylates

MA Battiste, F Tian, JM Baker, O Bautista…

Index: Journal of Fluorine Chemistry, , vol. 119, # 1 p. 39 - 51

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Citation Number: 15

Abstract

... Journal of Fluorine Chemistry. ... Department of Chemistry, University of Florida, Gainesville, FL 32611-7200 ... 1. The planar geometry of the CF 2 + site of 4a, and its unusually short CF bonds (1.272 Å) are consistent with stabilization of the carbocation by its fluorine substituents. ...