Reaction of divinyl telluride with secondary phosphine chalcogenides

NK Gusarova, NA Chernysheva, SV Yas'ko…

Index: Gusarova; Chernysheva; Yas'ko; Klyba; Trofimov Russian Journal of General Chemistry, 2011 , vol. 81, # 12 p. 2506 - 2509

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Citation Number: 8

Abstract

Abstract Divinyl telluride reacted with 2 equiv of diphenylphosphine sulfide in the presence of AIBN as radical initiator (63–68° C) to give the corresponding anti-Markovnikov adduct in 68% yield with high regioselectivity. Treatment of the addition product with aqueous hydrogen peroxide at room temperature afforded 71% of vinyldiphenylphosphine oxide. Radical addition of diphenylphosphine selenide to divinyl telluride (AIBN, 63–68° C) led to ...