A novel method for the conversion of halide anion to the positive halogen by nitrobenzenesulfonyl peroxide. Application to oxyhalogenation of olefin.

…, H Mochizuki, T Suzuki, N Kamigata

Index: Yoshida, Masato; Mochizuki, Hideki; Suzuki, Takashi; Kamigata, Nobumasa Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 12 p. 3704 - 3706

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Citation Number: 12

Abstract

Bromide and chloride anions could be readily oxidized into positive halogens by treating with p-nitrobenzenesulfonyl peroxide. The positive halogens, thus formed, reacted with olefins to give epihalonium ions, which were trapped by oxygen nucleophiles inter-or intramolecularly to afford oxyhalogenated compounds.