Transition Metal Complexes Coordinated by an NAD (P) H Model Compound and their Enhanced Hydride??Donating Abilities in the Presence of a Base

A Kobayashi, H Konno, K Sakamoto…

Index: Konno, Hideo; Sakamoto, Kazuhiko; Ishitani, Osamu Angewandte Chemie, International Edition, 2000 , vol. 39, # 22 p. 4061 - 4063 Angewandte Chemie, 2000 , vol. 112, p. 4227 - 4229

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Citation Number: 26

Abstract

Abstract The ruthenium (II) and rhenium (I) complexes containing an NAD (P) H model compound, 1-benzyl-1, 4-dihydronicotinamide (BNAH), as ligand,[Ru (tpy)(bpy)(BNAH)] 2+(1 a) and [Re (bpy)(CO) 3 (BNAH)]+(1 b), were quantitatively produced by the reaction of