Stereochemistry of Nucleophilic Substitution of Menthyl Derivatives with Anion of Diphenylphosphine Oxide by an Action of Sodium Dihydridobis (2- …

…, Y Soeda, N Suzuki, M Yamada, K Tsunekawa…

Index: Yamashita, Mitsuji; Soeda, Yukio; Suzuki, Nobuyoshi; Yamada, Manabu; Tsunekawa, Kenji; et al. Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1871 - 1872 Title/Abstract Full Text Show Details Yamashita, Mitsuji; Suzuki, Nobuyoshi; Yamada, Manabu; Soeda, Yukio; Yamashita, Hiroaki; et al. Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 1 p. 219 - 222

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Citation Number: 8

Abstract

The reaction of an anion of diphenylphosphine oxide prepared by the action of sodium dihydridobis (2-methoxyethanolato) aluminate on the oxide with various menthyl or neomenthyl halides and sulfonates were studied to clarify the sterochemistry of the substitution. The reaction gave neomenthyl-and methyl-diphenylphosphine oxide in ratios from 100: 0 to 0: 100.