Fullerene Derivatives Functionalized with Diethylamino??Substituted Conjugated Oligomers: Synthesis and Photoinduced Electron Transfer

…, JF Nierengarten, B Delavaux??Nicot…

Index: Gegout, Aline; Nierengarten, Jean-Francois; Delavaux-Nicot, Beatrice; Duhayon, Carine; Saquet, Alix; Listorti, Andrea; Belbakra, Abdelhalim; Chiorboli, Claudio; Armaroli, Nicola Chemistry - A European Journal, 2009 , vol. 15, # 35 p. 8825 - 8833

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Citation Number: 10

Abstract

Abstract Diethylamino-substituted oligophenylenevinylene (OPV) building blocks have been prepared and used for the synthesis of two [60] fullerene–OPV dyads, F-D1 and F-D2, which exhibit different conjugation length of the OPV fragments. The electrochemical properties of these acceptor–donor dyads have been studied by cyclic voltammetry. The first reduction is always assigned to the fullerene moiety and the first oxidation centered on the ...