Novel Organic??Inorganic Hybrid Mesoporous Silica Supported Oxo??Vanadium Schiff Base for Selective Oxidation of Alcohols

S Verma, M Nandi, A Modak, SL Jain…

Index: Verma, Sanny; Nandi, Mahasweta; Modak, Arindam; Jain, Suman L.; Bhaumik, Asim Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1897 - 1902

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Citation Number: 42

Abstract

Abstract Novel organic-inorganic hybrid mesoporous materials containing diimine moieties inside the pore wall were used for the grafting of an oxo-vanadium Schiff base complex at the mesopore surface. The prepared catalyst was found to be highly active and selective for the oxidation of a variety of primary, secondary and α-hydroxy carbonyl compounds to the corresponding aldehydes, ketones and 1, 2-dicarbonyl compounds using tert-butyl ...