A novel catalyst containing a platinum complex in polyethylene glycol medium supported on silica gel for vapor-phase hydrosilylation of acetylene with trichlorosilane …

M Okamoto, H Kiya, H Yamashita…

Index: Okamoto, Masaki; Kiya, Hironari; Yamashita, Hiromi; Suzuki, Eiichi Chemical Communications, 2002 , # 15 p. 1634 - 1635

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Citation Number: 30

Abstract

Hydrosilylation of acetylene with trichlorosilane or trimethoxysilane was carried out using a vapor-phase flow reactor with use of tetraammineplatinum (II) chloride in polyethylene glycol medium supported on silica gel as a catalyst, which is an active and thermally stable supported liquid-phase catalyst prepared readily from easily available materials, tetraammineplatinum (II) chloride, polyethylene glycol and silica gel.