The Binary Selenium (IV) Azides Se (N3) 4,[Se (N3) 5]−, and [Se (N3) 6] 2−

TM Klapoetke, B Krumm, M Scherr…

Index: Klapoetke, Thomas M.; Krumm, Burkhard; Scherr, Matthias; Haiges, Ralf; Christe, Karl O. Angewandte Chemie - International Edition, 2007 , vol. 46, # 45 p. 8686 - 8690

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Citation Number: 32

Abstract

As a part of main-group azide chemistry, the area of binary chalcogen azides has sparked significant interest during the last years. Thus, a theoretical study of the nitrogen-rich sulfur compounds S (N3) n (n= 1–4) was carried out, which included the neutral sulfur (IV) azide S (N3) 4.[1] Furthermore, the binary tellurium azides [Te (N3) 3]+, Te (N3) 4,[Te (N3) 5]¿, and [Te (N3) 6] 2¿ have been synthesized and characterized.[2] The calculated structures of ...