Organic letters

Catalytic asymmetric addition of thiols to nitrosoalkenes leading to chiral non-racemic α-sulfenyl ketones

JM Hatcher, MC Kohler, DM Coltart

Index: Reese, Colin B.; Sanders, H. Paul Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2719 - 2724

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Citation Number: 13

Abstract

... Select a Journal or Book ... racemic 18 was prepared and combined with catalyst 14 in CH 2 Cl 2 . The product composition was analyzed after 1 h and showed a 50 ... figure Scheme 2. (a) Determination of Absolute Stereochemistry; (b) Proposed Nitrosoalkenes Intermediates. ...