Organic letters

Co (III)-Alkyl Complex-and Co (III)-Alkylperoxo Complex-Catalyzed Triethylsilylperoxidation of Alkenes with Molecular Oxygen and Triethylsilane

T Tokuyasu, S Kunikawa, A Masuyama…

Index: Organic Letters, , vol. 4, # 21 p. 3595 - 3598

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Citation Number: 58

Abstract

... Volume: Page: ... Organic Letters. ... To confirm the possibility of participation of Co(III)−alkylperoxo complex, we prepared the Co(III)−cumylperoxo complex 4 14 and investigated the peroxidation of alkene 1 with complex 4 (16 mol %) and Et 3 SiH (2 equiv) (Scheme ...