Aza-crown ether tethered with benzothiazole: Synthesis and optical spectral studies

SH Mashraqui, V Dhaval, S Subramanian…

Index: Mashraqui, Sabir H.; Dhaval, Vashi; Subramanian; Khan, Tabrez B. Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2006 , vol. 45, # 3 p. 815 - 819

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Citation Number: 4

Abstract

Abstract: Synthesis of a new fluoroionophore 2 encompassing aza-phenyl-crown and benzothiazole is described. The UV-Vis spectra of 2 are not altered with change in solvent polarity indicating the absence of solvatochromism. However, the fluorescence spectra are progressively red shifted in more polar solvents on account of increasing charge transfer character of the excited state. In the presence of trifluoroacetic acid (TFAA), protonation of ...