e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Bulletin des Sociétés Chimiques Belges

Photolyse De HI Dans Une Matrice Hydrocarbonée Vitreuse à 77 K

M De Laet, B Tilquin

Index: Laet, M. de; Tilquin, B. Bulletin des Societes Chimiques Belges, 1991 , vol. 100, # 2 p. 97 - 105

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Citation Number: 0

Abstract

Abstract Stable products from the photolysis of HI in methyl-3 pentane (3 MP) or dimethyl-2, 3 butane (23 DMB) quenched solid at 77 K are analyzed by capillary gas chromatography. Selective formation of a tertiary radical is proposed for the 23 DMB/HI system; in 3 MP/HI, CH bond rupture is also localized at the weakest tertiary bond, however the scission is not selective.

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,3,4,4,5-hexamethylhexane Structure

2,3,3,4,4,5-hex...

2,3,5,5,6-pentamethylhept-2-ene Structure

2,3,5,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,5,5,6-pentamethylhept-2-ene Structure

2,3,5,5,6-penta...

2,3,3,6-tetramethyl-5-methylideneheptane Structure

2,3,3,6-tetrame...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~85%

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,3,5,6-pentamethylheptane Structure

2,3,3,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

1-Iodo-2-methylpropane Structure

1-Iodo-2-methyl...

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

rac-2,3-dimethyl-1-iodobutane Structure

rac-2,3-dimethy...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

1-Iodo-2-methylpropane Structure

1-Iodo-2-methyl...

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,3,4,4,5-hexamethylhexane Structure

2,3,3,4,4,5-hex...

2,3,5,5,6-pentamethylhept-2-ene Structure

2,3,5,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,5,5,6-pentamethylhept-2-ene Structure

2,3,5,5,6-penta...

2,3,3,6-tetramethyl-5-methylideneheptane Structure

2,3,3,6-tetrame...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~0%

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,3,5,6-pentamethylheptane Structure

2,3,3,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

rac-2,3-dimethyl-1-iodobutane Structure

rac-2,3-dimethy...

2,3,3,5,6-pentamethylheptane Structure

2,3,3,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

1-Iodo-2-methylpropane Structure

1-Iodo-2-methyl...

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,3,4,4,5-hexamethylhexane Structure

2,3,3,4,4,5-hex...

2,3,5,5,6-pentamethylhept-2-ene Structure

2,3,5,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

1-Iodo-2-methylpropane Structure

1-Iodo-2-methyl...

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

rac-2,3-dimethyl-1-iodobutane Structure

rac-2,3-dimethy...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

1-Iodo-2-methylpropane Structure

1-Iodo-2-methyl...

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

Detail

Pentane, 3-methyl- Structure

Pentane, 3-methyl-

~0%

3-iodo-3-methylpentane Structure

3-iodo-3-methyl...

2-iodo-3-methyl-pentane Structure

2-iodo-3-methyl...

neopentyl iodide Structure

neopentyl iodide

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~0%

2-iodo-2,3-dimethylbutane Structure

2-iodo-2,3-dime...

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,3,5,6-pentamethylheptane Structure

2,3,3,5,6-penta...

Detail

2,3-Dimethylbutane Structure

2,3-Dimethylbutane

~%

Octane, 2,3,6,7-tetramethyl- Structure

Octane, 2,3,6,7...

2,3,5,5,6-pentamethylhept-2-ene Structure

2,3,5,5,6-penta...

2,3,3,6-tetramethyl-5-methylideneheptane Structure

2,3,3,6-tetrame...

Detail

Action of di-tert-butylperoxide or of. gamma.-radiations on ...

[Gouverneur,P.J.L. Journal of Organic Chemistry, 1977 , vol. 42, p. 3051 - 3057]

Action of di-tert-butylperoxide or of. gamma.-radiations on ...

[Gouverneur,P.J.L. Journal of Organic Chemistry, 1977 , vol. 42, p. 3051 - 3057]