Tetrahedron

Stereoselective synthesis of polyenic alarm pheromones of cephalaspidean molluscs

R Alvarez, M Herrero, S López, AR de Lera

Index: Alvarez, Rosana; Herrero, Maria; Lopez, Susana; De Lera, Angel R. Tetrahedron, 1998 , vol. 54, # 24 p. 6793 - 6810

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Citation Number: 29

Abstract

The stereospecific thallium-accelerated palladium-catalyzed cross-coupling of 1-alkenyl boronic acids and 1-alkenyl iodides (the Suzuki reaction) is the key step in an efficient approach to several polyenic pheromones isolated from cephalaspidean opisthobranch molluscs.

 Related Synthetic Route
N/A Structure

59239-47-3

N/A

~%

(3E,5E,7E,9E)-10-Phenyl-3,5,7,9-decatetren-2-one Structure

62695-68-5

(3E,5E,7E,9E)-1...

(2E,4E)-5-iodo-penta-2,4-dien-1-ol Structure

163395-63-9

(2E,4E)-5-iodo-...

~%

(3E,5E,7E,9E)-10-Phenyl-3,5,7,9-decatetren-2-one Structure

62695-68-5

(3E,5E,7E,9E)-1...

5-iodopenta-2,4-dienal Structure

168295-35-0

5-iodopenta-2,4...

~%

(3E,5E,7E,9E)-10-Phenyl-3,5,7,9-decatetren-2-one Structure

62695-68-5

(3E,5E,7E,9E)-1...

(3E,5E)-6-iodohexa-3,5-dien-2-ol Structure

210531-47-8

(3E,5E)-6-iodoh...

~%

(3E,5E,7E,9E)-10-Phenyl-3,5,7,9-decatetren-2-one Structure

62695-68-5

(3E,5E,7E,9E)-1...

N/A Structure

186895-65-8

N/A

~%

(3E,5E,7E,9E)-10-Phenyl-3,5,7,9-decatetren-2-one Structure

62695-68-5

(3E,5E,7E,9E)-1...

METHYLLITHIUM Structure

917-54-4

METHYLLITHIUM

(2E,4E,6E,8E)-9-(pyridin-3-yl)nona-2,4,6,8-tetraenal Structure

210531-51-4

(2E,4E,6E,8E)-9...

~69%

10-pyridin-3-yldeca-3,5,7,9-tetraen-2-ol Structure

62695-70-9

10-pyridin-3-yl...

2-Propenal,3-(3-pyridinyl)- Structure

28447-15-6

2-Propenal,3-(3...

~%

10-pyridin-3-yldeca-3,5,7,9-tetraen-2-ol Structure

62695-70-9

10-pyridin-3-yl...

(2E,4E,6E,8E)-9-(pyridin-3-yl)nona-2,4,6,8-tetraen-1-ol Structure

210531-50-3

(2E,4E,6E,8E)-9...

~%

10-pyridin-3-yldeca-3,5,7,9-tetraen-2-ol Structure

62695-70-9

10-pyridin-3-yl...

(1E,3E)-1-iodo-4-(3-pyridyl)-buta-1,3-diene Structure

210531-48-9

(1E,3E)-1-iodo-...

~%

10-pyridin-3-yldeca-3,5,7,9-tetraen-2-ol Structure

62695-70-9

10-pyridin-3-yl...

N/A Structure

59239-47-3

N/A

~%

3-methyl-10-phenyldeca-3,5,7,9-tetraen-2-one Structure

73414-54-7

3-methyl-10-phe...

3-Bromopyridine Structure

626-55-1

3-Bromopyridine

1-Hexen-6-ol Structure

821-41-0

1-Hexen-6-ol

~%

6-pyridin-3-ylhexan-1-ol Structure

88940-83-4

6-pyridin-3-ylh...


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