The Journal of Organic Chemistry

Chemistry of gem-Dihalocyclopropanes. II. 1 The Reaction of Dienes with Dibromocarbene

L Skattebøl

Index: Skattebol,L. Journal of Organic Chemistry, 1964 , vol. 29, p. 2951 - 2956

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Citation Number: 56

Abstract

CH= CHCtt Brl a The yields are, where not otherwise stated, based on the olefin. d Yield of total mixture of I11 and IV. adducts B, in order to study their reactions with alkyllithium. We had previously shown that alkyl-and aryl-substituted gem-dibroniocyclopropanes reacted readily with methyl-or n-butyllithiuni to give, in niost cases, good yields of allenes. K Similar results were also independently obtained by Moore and Ward. $