Photochemistry of alkyl halides. 10. Vinyl halides and vinylidene dihalides

PJ Kropp, SA McNeely, RD Davis

Index: Kropp, Paul J.; McNeely, Steven A.; Davis, Robert Drummond Journal of the American Chemical Society, 1983 , vol. 105, # 23 p. 6907 - 6915

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Citation Number: 72

Abstract

Abstract: The photobehavior of the acyclic vinyl iodide 2, the I-iodocycloalkenes 11-14 and 39, the (ha1omethylene) cycloalkanes 45-48, and the (dihalomethy1ene) cyclohexanes 62- 64 has been studied. Except for the dichloride 64, which exhibited only radical behavior, each of the halides afforded a mixture of ionic and radical products. The two bromides studied, 48 and 63, afforded lower ratios of ionic to radical products than the ...