Journal of the American Chemical Society

Facile heterolysis of a carbon-carbon bond. Arylazodicyanomethanides as the leaving group capable of generating tert-cumyl cation and the hydrogen-bond- …

T Mitsuhashi

Index: Mitsuhashi Tsutomu Journal of the American Chemical Society, 1986 , vol. 108, # 9 p. 2394 - 2400

Full Text: HTML

Citation Number: 17

Abstract

Abstract: Decompositions of (p-nitropheny1) azo-terr-cumylmalonitrile in polar solvents were found to proceed via the heterolysis of a carbon-carbon bond to generate tert-cumyl cation and the conjugate base of (p-nitropheny1) hydrazonomalononitrile. The major products arising from tert-cumyl cation are as follows: tert-cumyl methyl ether in methanol, the N- cumylpyridinium hydrazonide in pyridine, and a-methylstyrene in M e 3 0 and in DMF. The ...

~99%

~80%

Detail

Detail

Infrared photochemistry of bicyclopropyl

[Farneth, William E.; Thomsen, Marcus W. Journal of the American Chemical Society, 1983 , vol. 105, # 7 p. 1843 - 1848]

Electron-transfer photochemistry of iminium salts. Olefin ph...

[Stavinoha,J.L.; Mariano,P.S. Journal of the American Chemical Society, 1981 , vol. 103, p. 3136]

Preparation and ring-opening of benzylic and allylic cyclopr...

[Ogle, Craig A.; Black, Kristyna C.; Sims, Philip F. Journal of Organic Chemistry, 1992 , vol. 57, # 12 p. 3499 - 3503]

Is 2-cyclopropylpropene really gauche?

[Durig, James R.; Zheng, Chao; Marzluf, Kathleen R.; Marquez, Gerardo B.; Guirgis, Gamil A.; Wurrey, Charles J.; Kilway, Kathleen V. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2005 , vol. 61, # 7 p. 1357 - 1373]

Mercury-photosensitized reactions of 1, 4-dienes

[Meinwald,J.; Smith,G.W. Journal of the American Chemical Society, 1967 , vol. 89, p. 4923 - 4932]