Mechanisms of photochemical reactions in solution. 77. The effect of configuration in some bicyclic di-. pi.-methanes with simple chromophores

RG Weiss, GS Hammond

Index: Weiss,R.G.; Hammond,G.S. Journal of the American Chemical Society, 1978 , vol. 100, p. 1172 - 1182

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Citation Number: 5

Abstract

Summary The similar coordination chemistry of Pu (1V) and Fe (II1) in vitro and in vivo has led to a biomimetic approach in the synthesis of specific sequestering agents for Pu (1V) and other actinide (1V) ions. The octadentate chelating agents 6 and 7 have been prepared and their coordination properties and biological activity are under investigation. Both 6 and 7 are much less susceptible to hydrolysis than is enterobactin and both 6 and 7 are less ...