Synthesis

Supramolecular Side-Chain Functionalized Polymers: Synthesis and Self-Assembly Behavior of Polynorbornenes Bearing PdII SCS Pincer Complexes

JM Pollino, M Weck

Index: Pollino, Joel M.; Weck, Marcus Synthesis, 2002 , # 9 p. 1277 - 1285

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Citation Number: 42

Abstract

Abstract A new polynorbornene bearing palladated SCS pincer complexes at each repeat unit has been synthesized using ring-opening metathesis polymerization. Small mesogenic molecules possessing nitrile or pyridine-based anchoring units are instantaneously and quantitatively coordinated to the palladium center in one simple self-assembly step giving rise to a densely functionalized polymer. These results suggest that the coordination of ...