Organometallics

Metal complexes of chiral NHCs containing a fused six-and seven-membered central ring

PD Newman, KJ Cavell, BM Kariuki

Index: Rueedi, Georg; Hansen, Hans-Juergen Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989

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Citation Number: 40

Abstract

... are strong σ-donors with a low capacity for π-acceptance(5) and their steric features are best described by a “buried volume” model(6 ... more chiral elements, which may be a classic stereogenic tetrahedral carbon or another form of asymmetry such as a chiral axis.(8) The source ...