Derivatives of Sulfenic Acids. IV. The Reaction of 2, 4-Dinitrobenzenesulfenyl Chloride with Aromatic Systems1

CM Buess, N Kharasch

Index: Buess; Kharasch Journal of the American Chemical Society, 1950 , vol. 72, p. 3529,3530

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Citation Number: 25

Abstract

In the course of studies to establish the existence of the 2, 4-dinitrobenzenesulfenium ion,(NO&C6H3Sf, in the bright-red solutions of 2, 4-dinitrobenzenesulfenyl chloride in sulfuric acid, a it was found that these solutions were decolorized by the addition of benzene, and that phenyl 2, 4-dinitrophenyl sulfide could be isolated from the reaction mixtures. This suggested that reagents which would promote the ionic dissociation of the ...