Platinum complex-catalysed carbonylations of organic lodides having β-hydrogens attached to sp 3-carbons

R Takeuchi, Y Tsuji, Y Watanabe

Index: Takeuchi, Ryo; Tsuji, Yasushi; Watanabe, Yoshihisa Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 351 - 352

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Citation Number: 9

Abstract

Transition metal-catalysed carbonylations of organic halides have been extensively studied. Among the transition metal catalysts, palladium complexes show high catalytic activity under rather mild reaction conditions.2J In the palladium- catalysed reactions, however, organic halides having P-hydrogens attached to sp3-carbons could not be effectively carbonylated, since intermediate a-alkyl palladium species generated by oxidative addition of the halides to the metal ...