Tetrahedron

Palladium on carbon-catalyzed solvent-free and solid-phase hydrogenation and Suzuki–Miyaura reaction

Y Monguchi, Y Fujita, S Hashimoto, M Ina, T Takahashi…

Index: Monguchi, Yasunari; Fujita, Yuki; Hashimoto, Shota; Ina, Mariko; Takahashi, Tohru; Ito, Ryo; Nozaki, Kei; Maegawa, Tomohiro; Sajiki, Hironao Tetrahedron, 2011 , vol. 67, # 45 p. 8628 - 8634

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Citation Number: 22

Abstract

The solvent-free and solid-phase hydrogenation of various reducible functionalities was efficiently catalyzed by heterogeneous palladium on carbon (Pd/C) under ambient hydrogen pressure and temperature. The Pd/C-catalyzed Suzuki–Miyaura coupling reaction between solid aryl bromides and solid arylboronic acids to generate the corresponding solid biaryls was also achieved under the totally solid-phase conditions.