ARKIVOC

The reactions of 4-chloro-2-butanol and 3-chloro-1-butanol with aqueous sodium hydroxide, and 1-chloro-2-propanol and 2-chloro-1-propanol with isopropyl …

…, K Aaljoki, MR Lyytinen, ML Huusko, M Hotokka

Index: Pihlaja, Kalevi; Aaljoki, Kari; Lyytinen, Maija-Riitta; Huusko, Marja-Liisa; Hotokka, Marjut Arkivoc, 2011 , vol. 2011, # 5 p. 188 - 199

Full Text: HTML

Citation Number: 0

Abstract

Abstract The total reaction of 4-chloro-2-butanol 1 with NaOH (aq) is dominated (74%) by intramolecular substitution (SNi), besides which bimolecular substitution (SN2, 12%) and 1, 4-elimination (ie fragmentation, contrary to earlier arguments) exhibit a significant contribution (11%). The total reaction of 3-chloro-1-butanol 2 instead is dominated by 1, 4- (72%) and 1, 2-elimination (25%), the substitution reactions being just observable (SNi 2 ...

~71%

Detail

~26%

Chemical activation study of the reactions of methylene with...

[Frey, Henry M.; Pidgeon, Ivy M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1983 , vol. 79, p. 1237 - 1248]

Oxygen ylides-I.: Reactions of carbenes with oxetane

[Friedrich, Klaus; Jansen, Ulrich; Kirmse, Wolfgang Tetrahedron Letters, 1985 , vol. 26, # 2 p. 193 - 196]

Cadmium-photosensitized reaction of. GAMMA.-valerolactone an...

[Yamamoto, Shunzo; Takahoso, Hiroshi; Sueishi, Yoshimi; Nishimura, Norio Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 2038 - 2042]