Bis [4′-(4-anilino)-2, 2′∶ 6′, 2 ″-terpyridine] transition-metal complexes: electrochemically active monomers with a range of magnetic and optical properties for …

GD Storrier, SB Colbran, DC Craig

Index: Storrier, Gregory D.; Colbran, Stephen B.; Craig, Donald C. Journal of the Chemical Society - Dalton Transactions, 1997 , # 17 p. 3011 - 3028

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Citation Number: 60

Abstract

The new ligand 4′-(4-anilino)-2,2′∶6′,2″-terpyridine (L 1 ) and a range of its transition-metal complexes have been prepared. The crystal and molecular structures of L 1 and [CuL 1 2 ][PF 6 ] 2 have been determined. Model reactions show that L 1 and its transition-metal complexes can be functionalised with suitable organic reagents: reactions with aromatic dianhydrides give imide derivatives, reactions with acid chlorides afford amide ...