Tetrahedron

An unexpected synthesis of 7-azidofurazano [3, 4-b] tetrazolopyrazine

S Guillou, G Jacob, F Terrier, R Goumont

Index: Guillou; Jacob; Terrier; Goumont Tetrahedron, 2009 , vol. 65, # 43 p. 8891 - 8895

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Citation Number: 8

Abstract

In the course of our program focused on the preparation of high-nitrogen content heterocyclic compounds, we wish to report an original synthesis of the tricyclic 7- azidofurazano [3, 4-b] tetrazolopyrazine via an unprecedented reaction between 2, 6- dimethoxy-3, 5-dinitropyrazine and hydrazine hydrate. This compound was identified by an X-ray diffraction analysis. Further studies of its structure by 15N and 13C NMR ...