Synlett

Sc (OTf) 3-and TfOH-catalyzed baeyer-villiger oxidation of carbonyl compounds with m-chloroperbenzoic acid

H Kotsuki, K Arimura, T Araki, T Shinohara

Index: Kotsuki, Hiyoshizo; Arimura, Koji; Araki, Tomohiro; Shinohara, Toshio Synlett, 1999 , # 4 p. 462 - 464

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Citation Number: 42

Abstract

Abstract: An efficient method for Baeyer-Villiger oxidation of carbonyl compounds to the corresponding esters/lactones has been developed using m-chloroperbenzoic acid in the presence of a catalytic amount of Sc (OTf) 3 or TfOH. Key words: Baeyer-Villger oxidation, m- CPBA, Sc (OTf) 3, TfOH

~86%

~99%

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