Palladium-Catalyzed Coupling of Organolead Compounds with Olefins

…, SC Choi, HC Ryu, T Yamaguchi

Index: Kang, Suk-Ku; Choi, Sang-Chul; Ryu, Hyung-Chul; Yamaguchi, Tokutaro Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5748 - 5749

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Citation Number: 22

Abstract

The palladium-catalyzed coupling of organic electrophiles (ie, halides and triflates) with alkenes (Heck-type coupling) 1 is now recognized to be an extremely useful and convenient method for the formation of carbon-carbon bonds in the synthesis of valuable products under mild conditions. The introduction of new reagents would expand the scope of the cross- coupling and the Heck-type reactions. Main group metals such as lead (IV), 2 bismuth, 3 ...