Organometallics

Formation of. mu.-silylene. mu.-hydrido manganese-platinum heterobimetallics via oxidative addition of (OC) 5MnSiR2H to zero-valent platinum compounds and the …

J Powell, JF Sawyer, M Shiralian

Index: Powell, John; Sawyer, Jeffery F.; Shiralian, Mahmoud Organometallics, 1989 , vol. 8, p. 577 - 583

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Citation Number: 17

Abstract

A wide variety of compounds containing transitionmetal-silicon bonds are known.'i2 One general synthetic method involves oxidative addition of organosilanes, R3SiH, to low-valent transition-metal The first example of such a reaction was reported by Chalk and Harrod3 (eq 1). This method was later widely used to