e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
The Journal of Organic Chemistry
… rearrangements of 2-bromo-1-chloro-3-arylpropanes and 1-bromo-3-chloro-2-arylpropanes. Evidence for a competitive bromine-assisted pathway in the case of 1, 2- …
D Fain, JE Dubois
Index: Fain, Dominique; Dubois, Jacques-Emile Journal of Organic Chemistry, 1987 , vol. 52, # 2 p. 260 - 267
CL CL tained by bromination of a 3-arylpropene or by abstracting a bromide ion from a 1, 2- dibromo-3-arylpropane. Two isomeric intermediates can be envisaged: a 3- arylpropylenebromonium ion and the (3-bromopropy1ene)-benzenium ion la (Scheme I). Not a great deal is known about benzenium ions bearing electron-withdrawing group^.^^^(3- Halopropy1ene) benzenium ions themselves were revealed primarily by our~ ork.~.~ ...