A family of hydride complexes of rhodium. Crystal structure of the paramagnetic rhodium (III)–rhodium (II) complex [(triphos) Rh (µ-H) 3 Rh (triphos)](BPh 4) 2· DMF [ …

C Bianchini, C Mealli, A Meli, M Sabat

Index: Bianchini, Claudio; Mealli, Carlo; Meli, Andrea; Sabat, Michal Journal of the Chemical Society, Chemical Communications, 1986 ,  # 10  p. 777 - 779

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Citation Number: 7

Abstract

A family of rhodium hydrides including mono-and bi-cuclear, mono-and poly-hydride, diamagnetic and paramagnetic members has been prepared; the structure of the paramagnetic rhodium hydride [(triphose) Rh (µ-H) 3Rh (triphos)](BPh4) 2· DMF [triphos= MeC (CH2PPh2) 3, DMF= dimethylformamide] has been established by X-ray methods; three hydride ligands bridge two rhodium atoms which are separated by a short distance [ ...