e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
New insights into the mechanism of triplet radical-pair combinations. The persistent radical effect masks the distinction between in-cage and out-of-cage processes
…, J Mohanty, WM Nau, U Bhattacharjee…
Index: Chesta, Carlos A.; Mohanty, Jyotirmayee; Nau, Werner M.; Bhattacharjee, Urbashi; Weiss, Richard G. Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 5012 - 5022
Steady-state and laser-pulsed irradiations of dibenzyl ketone (ACOB0) and derivatives with a p-methyl or a p-hexadecyl chain (ACOB1 and ACOB16, respectively) have been conducted in polyethylene films with 0, 46, and 68% crystallinities. Calculation of the fractions of in-cage combinations of the triplet benzylic radical-pair intermediates based on photoproduct yields, F c, from ACOB16 are shown to be incorrect as a result of the kinetic ...
