Water-Soluble Phosphines. 6.1 Tailor-Made Syntheses of Chiral Secondary and Tertiary Phosphines with Sulfonated Aromatic Substituents: Structural and Quantum …

…, A Hessler, M Kühnel, K Rettig, O Stelzer…

Index: Langhans, Klaus P.; Stelzer, Othmar Chemische Berichte, 1987 , vol. 120, p. 1707 - 1712

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Citation Number: 41

Abstract

Chiral water-soluble secondary phosphines were obtained selectively by nucleophilic phosphination of fluorobenzene derivatives Ar* F (Ar*= C6H4-4-SO3K, C6H4-2-SO3K, C6H3-2, 4-(SO3) K) 2) with RPH2 (R= Ph, 2, 4, 6-Me3C6H2, 2, 4, 6-iPr3C6H2) in superbasic