e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Unsaturated eight-membered ring compounds. X. 1, 2, 3, 4, 7-cyclooctapentaene, a possible intermediate in the conversion of cis, cis-3, 5-octadiene-1, 7-diyne to …
GH Mitchell, F Sondheimer
Index: Mitchell,G.H.; Sondheimer,F. Journal of the American Chemical Society, 1969 , vol. 91, p. 7520 - 7521
An indication that the interesting diallenic cyclic hydrocarbon 3 is indeed an intermediate in the transformation of 2 to 4 was obtained from hydrogenation experiments. Platinum oxide in ethanol and aqueous sodium hydroxide was reduced by stirring in hydrogen, a solution of 1 in ethanol was added, and the hydrogenation was continued until uptake ceased. Analysis by glpc showed that one of the components of the resulting complex mixture was ...
