Intermolecular Binding Modes in a Novel [1+ 1] Condensation 1 H-Pyrazole Azamacrocycle: A Solution and Solid State Study with Evidence for CO2 Fixation

…, S Blasco, J Ferrando-Soria, E García-España

Index: Belda, Raquel; Pitarch-Jarque, Javier; Soriano, Conxa; Llinares, Jose M.; Blasco, Salvador; Ferrando-Soria, Jesus; Garcia-Espana, Enrique Inorganic Chemistry, 2013 , vol. 52, # 19 p. 10795 - 10803

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Citation Number: 3

Abstract

Many ligands have been built with a pyrazole unit spacing two either equivalent or different coordination sites with the idea of placing two interconnected metal ions in close proximity in order to explore their electronic and magnetic interactions (see Scheme 2).(3, 5-8) Other spacers containing two adjacent nitrogen atoms able to provide similar organizations are piridazines,(9, 10) 1,2,4,5-tetraazines ,(11) 1,2,4-triazoles,(12-14) 1,3,4-thiadiazoles, and 1,3,4- oxadiazoles.(15) In recent ...