Tetrahedron

Polyion complex stabilized palladium nanoparticles for Suzuki and Heck reaction in water

A Ohtaka, Y Tamaki, Y Igawa, K Egami, O Shimomura…

Index: Ohtaka, Atsushi; Tamaki, Yuji; Igawa, Yuta; Egami, Koji; Shimomura, Osamu; Nomura, Ryoki Tetrahedron, 2010 , vol. 66, # 30 p. 5642 - 5646

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Citation Number: 30

Abstract

Palladium nanoparticles stabilized by a polyion complex composed of poly {4- chloromethylstyrene-co-(4-vinylbenzyl) tributylammonium chloride} and poly (acrylic acid) were easily recovered by filtration after pH treatment. The polyion complex stabilized palladium nanoparticles have high catalytic activity for the Suzuki and Heck reactions in water.