Development of an enantiodivergent strategy for the total synthesis of (+)-and (-)-dragmacidin F from a single enantiomer of quinic acid

NK Garg, DD Caspi, BM Stoltz

Index: Elfehail, Fadia; Dampawan, Pimchit; Zajac, Walter Synthetic Communications, 1980 , vol. 10, # 12 p. 929 - 932

Full Text: HTML

Citation Number: 98

Abstract

... Volume: Page: ... 10 At the time of this synthetic effort, the absolute stereochemistry of natural dragmacidin F was not known; thus ... halogen-selective Suzuki fragment coupling, pyrroloboronic ester 12 was reacted with dibromide 27 (prepared from 9 + 10) 5 under ...