{4, 4'-Dimethyl-6, 6'-bis (1-morpholiniomethyl)-2, 2'-[1, 2-ethanediylbis (nitrilomethylidene-N)] diphenolato-O, O'} copper (II) diperchlorate monohydrate

S Shanmuga Sundara Raj, R Thirumurugan…

Index: Shanmuga Sundara Raj; Thirumurugan; Shanmugam; Fun, Hoong-Kun; Manonmani; Kandaswamy Acta Crystallographica Section C: Crystal Structure Communications, 1999 , vol. 55, # 6 p. 894 - 896

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Abstract

Abstract The crystal structure of the title compound,[Cu (C28H38-N404)](C104) 2" H20, shows that the CuH ion is in a distorted square-pyramidal environment. The average Cu--O and Cu--N bond lengths are 1.916 (2) and 1.936 (3),~, respectively. Both of the morpholino rings adopt a chair conformation. Even though enough chelat-ing centres are available to coordinate more than one metal atom, because of the steric interaction of the mor-pholino ...