Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Phosphorus-carbon diad halogenotropic transformations of P-halogenoylids 1,2 and α-halogenoalkylphosphines 3,4 are described. Kinetic studies reveal the monomolecular mechanism of 1a → 3a chlorotropic rearrangement. ... Phosphorus-carbon diad halogenotropic transformations of P- ...