Tetrahedron letters

A selective, sensitive probe for mercury (II) ions based on oxazine-thione

QQ Zhang, JF Ge, QF Xu, XB Yang, XQ Cao, NJ Li…

Index: Zhang, Qian-Qian; Ge, Jian-Feng; Xu, Qing-Feng; Yang, Xue-Bo; Cao, Xue-Qin; Li, Na-Jun; Lu, Jian-Mei Tetrahedron Letters, 2011 , vol. 52, # 5 p. 595 - 597

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Citation Number: 19

Abstract

A selective, sensitive probe for Hg (II) ions, 7-(diethylamino)-3-methyl-2H-benzo [b][1, 4] oxazine-2-thione (1), is developed. Compound 1 behaves as a ratiometric probe, exhibiting a large blue shift of 100nm in its absorption spectra upon exposure to Hg (II) ions. The dramatic color change of the solution made 'naked-eye'detection of Hg (II) ions possible. Emission spectra of 1 displayed a selective enhancement in intensity in the presence of ...