Design and development of cyclometalated ruthenium complexes containing thiophenyl-pyridine ligand for dye-sensitized solar cells

CY Li, C Su, HH Wang, P Kumaresan, CH Hsu, IT Lee…

Index: Li, Chung-Yen; Su, Chaochin; Wang, Hsiou-Hsuan; Kumaresan, Prabakaran; Hsu, Chia-Hsuan; Lee, I-Ting; Chang, Wei-Chun; Tingare, Yogesh S.; Li, Ting-Yu; Lin, Chia-Feng; Li, Wen-Ren Dyes and Pigments, 2014 , vol. 100, # 1 p. 57 - 65

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Citation Number: 21

Abstract

Abstract Two new cyclometalated ruthenium sensitizers NC102 (1) and NC103 (2), where the two NCS-ligands of the N3 analog were replaced with the 2-thiophen-2-yl-pyridine and 2- benzo [b] thiophen-2-yl-pyridine ligands, respectively, were designed and synthesized for dye-sensitized solar cell applications. The effects of these two ligands on the photophysical behavior of ruthenium complexes were investigated by their optical, electrochemical, and ...