A Silver??Catalyzed Spirocyclization of Alkynyl Silyl Enol Ethers

C Schäfer, M Miesch, L Miesch

Index: Schaefer, Christian; Miesch, Michel; Miesch, Laurence Chemistry - A European Journal, 2012 , vol. 18, # 26 p. 8028 - 8031

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Citation Number: 6

Abstract

Spiro compounds are of great interest because of their special conformational features and their structural implications on biological systems.[1] The presence of the sterically constrained spiro structure in various natural products substantially promotes interest in the investigation of spiro compounds.[2] The Conia-ene cyclization is one of the processes during which a quaternary center is formed by the pericyclic reaction of an enolizable ...