Polymer

… and characterization of comb-shaped carbazole containing copolymer via combination of ring opening polymerization and nitroxide-mediated polymerization

C Chang, J Zhu, Z Zhang, N Zhou, Z Cheng, X Zhu

Index: Chang, Cheng; Zhu, Jian; Zhang, Zhengbiao; Zhou, Nianchen; Cheng, Zhenping; Zhu, Xiulin Polymer, 2010 , vol. 51, # 9 p. 1947 - 1953

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Citation Number: 11

Abstract

The macro-TEMPO agent (poly (4-glycidyloxy-2, 2, 6, 6-tetramethylpiperidine-1-oxyl), PGTEMPO) was synthesized by anion ring-opening polymerization (ROP) of 4-glycidyloxy-2, 2, 6, 6-tetramethylpiperidine-1-oxyl (GTEMPO) using potassium t-butoxide as the initiator. The comb-shaped copolymer, PGTEMPO-g-PVBK, was prepared via nitroxide-mediated free radical polymerization (NMP) using PGTEMPO as macro-TEMPO agent and 9-(4- ...