Journal of organometallic chemistry

Preparation and characterization of mixed alkyl amido complexes of gallium

ST Barry, DS Richeson

Index: Barry, Sean T.; Richeson, Darrin S. Journal of Organometallic Chemistry, 1996 , vol. 510, # 1-2 p. 103 - 108

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Abstract

A series of primary amido gallium alkyl complexes that includes a base free dimer,[t Bu 2Ga (μ-N (H) tBu)] 2 (1), Lewis base stabilized monomeric complexes, nBu2Ga (N (H) tBu)(THF)(2) and nBu2Ga [NH (2, 6-Me2C6H3)] py (3) and an anionic complex, nBu2Ga [NH (2, 6-Me2C6H3)] 2 [Li (Et2O)](4) is reported. Complex 1 crystallizes in the triclinic space group P-1 (a= 10.265 (5) A ̊, b= 15.752 (6) A ̊, c= 8.932 (4) A ̊, α= 90.32 (3)°, β= ...